401 KAR 53:010reg. Ambient air quality standards


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  •       Section 1. Ambient Air Quality Standards. The primary and secondary ambient air quality standards for sulfur oxides, particulate matter, carbon monoxide, ozone, nitrogen dioxide, lead, hydrogen sulfide, gaseous fluorides, total fluorides, and odors are specified in Appendix A of this administrative regulation. Measurements shall[will] be made by methods and frequency specified in Section 2 of this administrative regulation.

     

          Section 2. Methods of Measurement. For those air contaminants for which there are state ambient air quality standards that are the same as the national ambient air quality standards, measurements shall be made in accordance with 40 C.F.R. Parts 50 and 53[according to reference methods, or their equivalent methods]. For other air contaminants for which there are state ambient air quality standards, measurements shall be made according to this administrative regulation, reference methods, or equivalent methods[established in 401 KAR 50:015, this administrative regulation, or as prescribed by the cabinet]. The frequency of measurements for all air contaminants shall be prescribed by the cabinet, in accordance with 40 C.F.R. Parts 50 and 53, 401 KAR 50:015, or this administrative regulation.

     

          Section 3. Within sixty (60) days of promulgation or revision of any primary or secondary ambient air quality standard by the U.S. EPA, the cabinet shall initiate proceedings to promulgate or review this administrative regulation in conformance with the federal ambient air quality standards. 

    APPENDIX A TO 401 KAR 53:010

    AMBIENT AIR QUALITY STANDARDS

    The following air contaminant concentrations shall apply to any single point location:

    Pollutant

    Primary Standard

    Secondary Standard

    Carbon Monoxide

    Eight (8) hour average

    One (1) hour average

     

    9 ppm(1) (10 mg/m3)

    35 ppm(1) (40 mg/m3)

     

    --

    --

    Lead

    Rolling three (3) month mean

     

    0.15 μg/m3

     

    Same as primary

    Nitrogen Dioxide

          Annual arithmetic mean

     

          One (1) hour average

     

    53 ppb (100 mg/m3)(2)

    100 ppb

     

    Same as primary

    --

    Ozone

          One (1) hour average

          Eight (8) hour average

                 2015 standard

                2008 standard

                1997 standard

     

    0.12 ppm(3)

     

    0.070 ppm

    0.075 ppm

    0.08 ppm(4)

     

    Same as primary(3)

     

    Same as primary

    Same as primary

    Same as primary(4)

    Particulate Matter, measured as PM10

          Twenty-four (24) hour average

     

    150 μg/m3

     

    Same as primary

    Particulate Matter, measured as PM2.5

          Annual arithmetic mean

                2012 standard

                2006 standard

                1997 standard

          Twenty-four (24) hour average

                2012 standard

                2006 standard

                1997 standard

     

     

     

    12.0 μg/m3

    15.0 μg/m3

    15.0 μg/m3

     

     

    35 μg/m3

    35 μg/m3

    65 μg/m3

     

     

    (5)

    Same as primary

    Same as primary

     

     

     

    (5)

    Same as primary

    Same as primary

    Sulfur Dioxide

          Annual arithmetic mean

          One (1) hour average

          Three (3) hour average

          Twenty-four (24) hour average

     

    0.030 ppm(1)(6)

    75 ppb

    --

    0.14 ppm(1)(6)

     

    --

    --

    0.5 ppm(1)

    --

    Gaseous Fluorides - (expressed as HF)

          Annual arithmetic mean

     

          One (1) month average

     

          One (1) week average

     

          Twenty-four (24) hour average

     

          Twelve (12) hour average

     

     

     

    400 μg/m3 (0.5 ppm)

     

    --

     

    --

     

    800 μg/m3(1) (1.0 ppm)

     

    --

     

     

    --

     

    0.82 μg/m(1) (1.00 ppb)

     

    1.64 μg/m3(1) (2.00 ppb)

     

    2.86 μg/m3(1) (3.50 ppb)

     

     

    3.68 μg/m3(1) (4.50 ppb)

    Hydrogen Sulfide

          One (1) hour average

     

    --

     

    14 μg/m3(1) (0.01 ppm)

    Odors

    --

    A mixture of one (1) volume of ambient air and seven (7) volumes of odorless air shall have no detectable odor at any time.

    Total Fluorides

    Dry weight basis (as fluoride ion) in and on forage for consumption by grazing ruminants:

     

    Average concentration of monthly samples over growing season (not to exceed six (6) consecutive months)

     

          Two (2) month average

     

          One (1) month average

     

     

     

     

     

     

     

    --

     

     

    --

     

    --

     

     

     

     

     

     

     

    40 ppm

     

     

    60 ppm

     

    80 ppm

    Footnotes:

    1 Average is not to be exceeded more than once per calendar year.

    2 The official level of the annual NO2 standard is 0.053 ppm, equal to fifty-three (53) ppb, which is shown for the purpose of clearer comparison to the one (1) hour standard.

    3 The U.S. Environmental Protection Agency revoked the one (1) hour ozone standard in all areas in 2005. However, some areas have continuing obligations under the standard.

    4 The U.S. Environmental Protection Agency revoked the 1997 eight (8) hour ozone standard in 2015. However, some areas have continuing obligations under the standard.

    5 The secondary ambient air quality standard was not adjusted from the previously established standard.

    6 The 1971 sulfur dioxide standards remain in effect until one (1) year after an area is designated for the 2010 standard, except that in areas designated nonattainment for the 1971 standards, the 1971 standards remain in effect until implementation plans to attain or maintain the 2010 standards are approved, in accordance with 40 C.F.R. Part 52, Subpart S.

     

    APPENDIX A TO 401 KAR 53:010

    AMBIENT AIR QUALITY STANDARDS

    The following air contaminant concentrations shall apply at any single point location:

    CONTAMINANT

    PRIMARY STANDARD

    SECONDARY STANDARD

    Sulfur Oxides (Sulfur Dioxide) mg/m3

    Annual Arithmetic Mean, not to exceed

    Maximum Twenty-Four-Hour Average

    Maximum Three-Hour Average

     

    80 (0.03 ppm)

    365 (0.14 ppm)1

    --

     

    --

    --

    1300 (0.50 ppm)1

    Particulate Matter, measured as PM10 - mg/m3

    Annual Arithmetic Mean, not to exceed

    Maximum Twenty-Four-Hour Average

     

    502

    1503

     

    502

    1503

    Carbon Monoxide - mg/m3

    Maximum Eight-Hour Average

    Maximum One-Hour Average

     

    10 (9 ppm)1

    40 (35 ppm)1

     

    Same as primary

    Same as primary

    Ozone - mg/m3

    Maximum Average

     

    235 (0.12 ppm)4

     

    Same as primary

    Nitrogen Dioxide - mg/m3

    Annual Arithmetic Mean, not to exceed

     

    100 (0.05 ppm)

     

    Same as primary

    Lead - mg/m3

    Maximum Arithmetic Mean averaged over a calendar quarter

     

    1.5

     

    Same as primary

    Hydrogen Sulfide - mg/m3

    Maximum One-Hour Average

     

    --

     

    14 (0.01 ppm)1

    Gaseous Fluorides - (expressed as HF) - mg/m3

    Annual Arithmetic Mean, not to exceed

    Maximum One-Month Average

    Maximum One-Week Average

    Maximum Twenty-Four-Hour Average

    Maximum Twelve-Hour Average

     

    400 (0.5 ppm)

    --

    --

    800 (1.0 ppm)1

    --

     

    --

    0.82 (1.00 ppb)1

    1.64 (2.00 ppb)1

    2.86 (3.50 ppb)1

    3.68 (4.50 ppb)1

    Total Fluorides - ppm

    Dry weight basis (as fluoride ion) in and on forage for consumption by grazing ruminants

    The following concentrations are not to be exceeded:

    Average concentration of monthly samples over growing season (not to exceed 6 consecutive months)

    Two-Month Average

    One-Month Average

     

     

     

     

     

    --

    --

    --

     

     

     

     

     

    40 ppm (w/w)

    60 ppm (w/w)

    80 ppm (w/w)

    Odors

     

    At any time when 1 volume unit of ambient air is mixed with 7 volume units of odorless air, the mixture must have no detectable odor.

    Footnotes:

    1This average is not to be exceeded more than once per year.

    2The standard is attained when the expected annual arithmetic mean concentration, as determined in accordance with Appendix K to 40 C.F.R. 50, is less than or equal to fifty (50) mg/m3.

    3The standard is attained when the expected number of days per calendar year with a twenty-four (24) hour average concentration above 150 mg/m3, as determined in accordance with Appendix K of 40 C.F.R. 50, is equal to or less than one (1).

    4The standard is attained when the expected number of days per calendar year with maximum hourly average concentrations above 0.12 ppm (235 mg/m3) is equal to or less than one (1), as determined by Appendix H of 40 C.F.R. 50.]

     

    CHARLES G. SNAVELY, Secretary

          APPROVED BY AGENCY: April 14, 2016

          FILED WITH LRC: April 14, 2016 at 11 a.m.

          CONTACT PERSON: Cassandra Jobe, Policy Analyst, Division for Air Quality, 200 Fair Oaks Lane, 1st Floor, Frankfort, Kentucky 40601, phone (502) 564-3999, fax (502) 564-4666, email Cassandra.Jobe@ky.gov.

Notation

      RELATES TO: KRS 224.20-100, 224.20-110, 224.20-120, 40 C.F.R. Parts 50, 51, 52, 53, 58, 75, 81, 42 U.S.C. 7401-7671q

      STATUTORY AUTHORITY: KRS 224.10-100(5), 42 U.S.C. 7401-7671q

      NECESSITY, FUNCTION, AND CONFORMITY: KRS 224.10-100(5) requires the [Environmental and Public Protection] cabinet to promulgate[prescribe] administrative regulations for the prevention, abatement, and control of air pollution. This administrative regulation establishes[is to fix] ambient air quality standards necessary for the protection of the public health, the general welfare, and the property and people in the[this] Commonwealth of Kentucky.